CobaltMaghrebV1, Main, Exploration, bibRecord, 000204

β-Xenophyllite-type Na4Li0.62Co5.67Al0.71(AsO4)6

Identifieur interne : 000204 ( Main/Exploration ); précédent : 000203; suivant : 000205

β-Xenophyllite-type Na4Li0.62Co5.67Al0.71(AsO4)6

Auteurs : Riadh Marzouki [Tunisie] ; Wafa Frigui [Tunisie] ; Abderrahmen Guesmi [Tunisie] ; Mohamed Faouzi Zid [Tunisie] ; Ahmed Driss [Tunisie]

Source :

Acta Crystallographica Section E: Structure Reports Online [ 1600-5368 ] ; 2013.

RBID : PMC:3790335

Abstract

The title compound, tetrasodium lithium cobalt aluminium hexa(orthoarsenate), was synthesized by a solid state reaction route. In the crystal structure, Co²⁺ ions are partially substituted by Al³⁺ in an octahedral environment [M1 with site symmetry 2/m; occupancy ratio Co:Al = 0.286 (10):0.714 (10)]. The charge compensation is ensured by Li⁺ cations sharing a tetrahedral site with Co²⁺ ions [M2 with site symmetry 2; occupancy ratio Co:Li = 0.690 (5):0.310 (5)]. The anionic unit is formed by two octahedra and three tetrahedra linked only by corners. The CoM1M2As₂O₁₉ units associate to an open three-dimensional framework containing tunnels propagating along the a-axis direction. One Na⁺ cation is located in the periphery of the tunnels while the other two are situated in the centres: all Na⁺ cations exhibit half-occupancy. The structure of the studied material is compared with those of various related minerals reported in the literature.

Url:

http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3790335

DOI: 10.1107/S1600536813025233
PubMed: 24098157
PubMed Central: 3790335

Affiliations:

Le document en format XML

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Li<sub>0.62</sub>
Co<sub>5.67</sub>
Al<sub>0.71</sub>
(AsO<sub>4</sub>
)<sub>6</sub>
</title>
<author><name sortKey="Marzouki, Riadh" sort="Marzouki, Riadh" uniqKey="Marzouki R" first="Riadh" last="Marzouki">Riadh Marzouki</name>
<affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences de Tunis, Université de Tunis ElManar, 2092 Manar II Tunis,<country>Tunisia</country>
</nlm:aff>
<country xml:lang="fr">Tunisie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
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<author><name sortKey="Frigui, Wafa" sort="Frigui, Wafa" uniqKey="Frigui W" first="Wafa" last="Frigui">Wafa Frigui</name>
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<country xml:lang="fr">Tunisie</country>
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<country xml:lang="fr">Tunisie</country>
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<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a" type="main">β-Xenophyllite-type Na<sub>4</sub>
Li<sub>0.62</sub>
Co<sub>5.67</sub>
Al<sub>0.71</sub>
(AsO<sub>4</sub>
)<sub>6</sub>
</title>
<author><name sortKey="Marzouki, Riadh" sort="Marzouki, Riadh" uniqKey="Marzouki R" first="Riadh" last="Marzouki">Riadh Marzouki</name>
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</nlm:aff>
<country xml:lang="fr">Tunisie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
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</nlm:aff>
<country xml:lang="fr">Tunisie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
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</nlm:aff>
<country xml:lang="fr">Tunisie</country>
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</nlm:aff>
<country xml:lang="fr">Tunisie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
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<front><div type="abstract" xml:lang="en"><p>The title compound, tetrasodium lithium cobalt aluminium hexa(orthoarsenate), was synthesized by a solid state reaction route. In the crystal structure, Co<sup>2+</sup>
 ions are partially substituted by Al<sup>3+</sup>
 in an octahedral environment [<italic>M</italic>
1 with site symmetry 2/<italic>m</italic>
; occupancy ratio Co:Al = 0.286 (10):0.714 (10)]. The charge compensation is ensured by Li<sup>+</sup>
 cations sharing a tetrahedral site with Co<sup>2+</sup>
 ions [<italic>M</italic>
2 with site symmetry 2; occupancy ratio Co:Li = 0.690 (5):0.310 (5)]. The anionic unit is formed by two octahedra and three tetrahedra linked only by corners. The Co<italic>M</italic>
1<italic>M</italic>
2As<sub>2</sub>
O<sub>19</sub>
 units associate to an open three-dimensional framework containing tunnels propagating along the <italic>a-</italic>
axis direction. One Na<sup>+</sup>
 cation is located in the periphery of the tunnels while the other two are situated in the centres: all Na<sup>+</sup>
 cations exhibit half-occupancy. The structure of the studied material is compared with those of various related minerals reported in the literature.</p>
</div>
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Serveur d'exploration sur le cobalt au Maghreb

β-Xenophyllite-type Na4Li0.62Co5.67Al0.71(AsO4)6

β-Xenophyllite-type Na4Li0.62Co5.67Al0.71(AsO4)6

Source :

Abstract

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	Serveur d'exploration sur le cobalt au Maghreb
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